Chlorosulfonic Acid

Front Cover
Royal Society of Chemistry, 2002 - Science - 307 pages
Since its discovery in 1854, chlorosulfonic acid has demonstrated that it is a truly versatile reagent. It is widely used as a sulfonating and chlorosulfonating agent, particularly of organic compounds, and it provides useful synthetic intermediates for many branches of industry. This book provides a detailed, up to date account of the reactions of chlorosulfonic acid with aliphatic, aromatic and heterocyclic compounds; reactions with elements and inorganic compounds are also discussed, along with the use of the reagent as a powerful acid catalyst, and halogenation and dehydrating agent. Finally, the commercial uses and manufacture of chlorosulfonic acid are reviewed. The detailed coverage in this book, coupled with the many references to recent work, will ensure that it is welcomed as a reference by synthetic chemists in, for example, the pharmaceutical, agrochemical, plastic and detergent industries. Researchers and their students in academia will also find it a valuable addition to their bookshelves.
 

Contents

Safety
5
Sulfonation by Halosulfonic Acids
11
References
20
Sulfonylation
30
2
39
Phenols
61
Aryl Ethers
71
Aromatic Amines and Related Compounds
97
Reactions of Chlorosulfonic Acid with Heterocyclic
181
Heterocyclic Oxygen Compounds
199
Sulfur Heterocycles
209
References
222
Inorganic Compounds
228
Commercial Uses of Chlorosulfonic Acid
235
Detergents
241
Blowing Agents
252

Arylureas
110
Reaction of Chlorosulfonic Acid with Miscellaneous Compounds
117
References
133
The Reaction of Chlorosulfonic Acid with Aliphatic
146
Alkyl Halides
153
Aliphatic Carbonyl Compounds
160
References
176
Cyclization
259
Rearrangement
265
Preparation Manufacture and Properties
272
Properties
276
Subject Index
294
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