High Pressure Geochemistry & Mineral Physics: Basics for Planetology and Geo-Material Science

Front Cover
Elsevier, Dec 11, 2004 - Science - 1272 pages
Significant achievements have been made at the cross-roads of physics and planetary science. In the second half of the twentieth century, the discipline of planetary sciences has witnessed three major episodes which have revolutionized its approach and content: (i) the plate-tectonic theory, (ii) human landing and discoveries in planetary astronomy and (iii) the extraordinary technical advancement in high P-T studies, which have been abetted by a vast improvement in computational methods. Using these new computational methods, such as first principles including ab initio models, calculations have been made for the electronic structure, bonding, thermal EOS, elasticity, melting, thermal conductivity and diffusivity.

In this monograph, the boundaries of the definitions of a petrologist, geochemist, geophysicist or a mineralogist have been willfully eliminated to bring them all under the spectrum of "high-pressure geochemistry" when they deal with any material (quintessentially a chemical assemblage) - terrestrial or extraterrestrial - under the conditions of high-pressure and temperature. Thus, a petrologist using a spectrometer or any instrument for high-pressure studies of a rock or a mineral, or a geochemist using them for chemical synthesis and characterization, is better categorized as a "high-pressure geochemist" rather than any other kind of disciplinarian.

The contents of this monograph bring together, under one cover, apparently disparate disciplines like solid-earth geophysics and geochemistry as well as material science and condensed-matter physics to present a thorough overview of high pressure geochemistry. Indeed, such interdisciplinary activities led to the discovery of new phenomena such as high P-T behaviour in metal oxides (e.g. Mott transition), novel transitions such as amorphization, changes in order-disorder in crystals and the anomalous properties of oxide melts.

 

Contents

The Earth and Planetary System
15
Cosmochemistry and Properties of Light Element Compounds
17
PetroTectonic Features of Terrestrial Planets
177
AB AB2 A2 B3 ABX3 ABX4 AB2 X4 and A2 B2 X7
283
Basics for Pressures Studies
319
Principles of Techniques
321
Crystalline Materials Under High Pressure
401
Mineral Systems
513
AB2 X4 Structure
673
ABX3 PerovskiteIlmenite Structure
711
Silicate Melts and Rocks
793
Simple Oxides and Carbonates
823
Hydrous Minerals
885
The Earths Core
967
Transport Properties at Deep Depths Related Condensed Matter Phenomena
1039
Transport Properties in Deep Depths and Related CondensedMatter Phenomena
1041

Olivines and Pyroxenes
515
K2 O Na2 O CaOAl2 O3 SiO2 System
613
Al2 O3 SiO2 and CaOMgOAl2 O3 SiO2 Systems
639
References
1103
Subject Index
1233
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Page 79 - Entropy also plays a role in the Third Law of Thermodynamics, which states that the entropy of a perfect crystal is zero at zero absolute temperature.
Page 90 - Extrapolation of thermodynamic data along the HDA-LDA co-existence line into the liquid region has led to the hypothesis that there might exist a second critical point for water and the speculation that liquid water is a mixture of two distinct structures with different densities (Mishima and Stanley, 1998b).

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