## Liquid-State Physical Chemistry: Fundamentals, Modeling, and ApplicationsFor many processes and applications in science and technology a basic knowledge of liquids and solutions is a must. Gaining a better understanding of the behavior and properties of pure liquids and solutions will help to improve many processes and to advance research in many different areas. This book provides a comprehensive, self-contained and integrated survey of this topic and is a must-have for many chemists, chemical engineers and material scientists, ranging from newcomers in the field to more experienced researchers. The author offers a clear, well-structured didactic approach and provides an overview of the most important types of liquids and solutions. Special topics include chemical reactions, surfaces and phase transitions. Suitable both for introductory as well as intermediate level as more advanced parts are clearly marked. Includes also problems and solutions. |

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### Contents

1952 | |

1958 | |

Basic Energetics Intermolecular Interactions | |

Describing Liguids Phenomenological Behavior | |

The Transition from Microscopic to Macroscopic | |

Describing Liguids Structure and Energetics | |

Approach | |

Modeling the Structure of Liguids The Simulation | |

Describing the Behavior of Liguids Polar Liguids | |

Mixing Liguids Ionic Solutions | |

Mixing Liguids Polymeric Solutions | |

Some Special Topics Reactions in Solutions | |

Some Special Topics Surfaces of Liguids | |

Some Special Topics Phase Transitions | |

Units Physical Constants and Conversion | |

### Common terms and phrases

activity coefficient approach approximation atoms average becomes behavior calculated cell chain Chapter charge Chem chemical potential component configuration consider constant contribution coordination number correlation function critical exponents Data from Ref defined denoted density derived described dipole dipole moment distance electrolytes electrons enthalpy entropy equation equilibrium estimate example expansion expression factor Figure fluid force Gibbs energy given hard-sphere Helmholtz energy Hence homogeneous function hydration hydrogen bonds indicated integral interaction intermolecular ionic ions kinetic lattice leads liquid matrix mixture molar mole fraction molecular molecules obtain parameter particles partition function permittivity phase Phys polarizability polarization polymer potential energy pressure Problem properties quantum radius reaction reference regular solution represents respectively rotation segments Show simulations solid solubility solvent spherical Statistical Mechanics structure temperature tensor term theory thermodynamic Tori transition vapor variables vector virial coefficient virial expansion volume