Organofluorine Chemistry: Principles and Commercial ApplicationsR.E. Banks, B.E. Smart, J.C. Tatlow During the past fifteen years commercial interest in compounds containing carbon fluorine bonds has burgeoned beyond all expectations, mainly owing to business opportunities arising from work on biologically active fluoroorganics-particularly agrochemicals, the relentless search for new markets for fluoropolymers and fluoro carbon fluids, developments in the field of medical diagnostics, and the drive to find replacements for ozone-depleting CFCs and Halon fire-extinguishing agents. Judging the situation to warrant the publication of a comprehensive collection of up-to-date reviews dealing with commercial organofluorine compounds within a single volume of manageable size (and hence reasonable cost), we were delighted to be invited by Plenum Publishing Corporation to produce a suitable book. In order to provide an authentic and wide-ranging account of current commercial applications of fluoroorganic materials, it clearly was necessary to assemble a sizeable team of knowledgeable contributing authors selected almost entirely from industry. Through their efforts we have been able to produce an almost complete coverage of the modem organofluorochemicals business in a manner designed to attract a reader ship ranging from experts in the field, through chemists and technologists currently unaware of the extent of industrial involvement with fluoroorganics, to students of applied chemistry. Promised chapters dedicated to perfluoroolefin oxides and 18F labeling of radiopharmaceuticals failed to materialize. This is somewhat unfortunate in view of our aim to achieve comprehensive coverage of the subject. |
Contents
1 | 1 |
2 | 25 |
52 | 43 |
Table 2 Continued | 52 |
3 | 57 |
4 | 89 |
PP25 | 94 |
HEADER TANK | 106 |
444 | 433 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 434 |
442 | 435 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 436 |
440 | 437 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 438 |
Dario Sianesi et al | 439 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 440 |
5 | 121 |
6 | 145 |
20 | 157 |
7 | 159 |
8 | 177 |
9 | 195 |
10 | 221 |
11 | 237 |
NO₂ CF3 | 241 |
12 | 263 |
helical axis | 265 |
13 | 287 |
13 | 315 |
O₂N | 318 |
14 | 321 |
15 | 339 |
16 | 373 |
HFP | 378 |
17 | 397 |
18 | 403 |
19 | 413 |
454 | 423 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 424 |
452 | 425 |
Z DOL | 426 |
450 | 427 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 428 |
448 | 429 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 430 |
446 | 431 |
Table 3 Physical Properties of Galden Fractions | 432 |
436 | 441 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 442 |
434 | 443 |
Perfluoropolyethers from Perfluoroolefin Photooxidation | 444 |
432 | 445 |
20 | 446 |
Monomers and Polymers from Hexafluoroacetone | 448 |
428 | 449 |
Monomers and Polymers from Hexafluoroacetone | 450 |
426 | 451 |
Scheme 7 Polyimide derived from the HFIPbridged tetraacid | 452 |
20 | 453 |
Monomers and Polymers from Hexafluoroacetone | 454 |
21 | 463 |
22 | 469 |
480 | 480 |
23 | 483 |
5 nm | 486 |
4 | 497 |
24 | 501 |
543 | |
26 | 555 |
12 | 569 |
27 | 579 |
CF2CF2 | 588 |
593 | |
27 | 595 |
27 | 609 |
28 | 617 |
Other editions - View all
Organofluorine Chemistry: Principles and Commercial Applications R.E. Banks,B.E. Smart,J.C. Tatlow Limited preview - 2013 |
Organofluorine Chemistry: Principles and Commercial Applications R.E. Banks,B.E. Smart,J.C. Tatlow No preview available - 2013 |
Common terms and phrases
acid agents anode applications aqueous aromatic Asahi Glass Co atoms Bayer C-F bonds catalyst CF3 CF3 CFCs Chapter Chem chemical chlorine chlorofluorocarbons Ciba-Geigy commercial compounds containing copolymers crystalline Daikin derivatives developed Du Pont DuPont dyes dyestuffs effects elastomers electrochemical electron ether European Patent fluids fluorinated carbon fluorine Fluorine Chem Fluorine Chemistry fluorine-containing fluoroaromatic fluorocarbon Fluorochemical fluoroelastomers fluoropolymers German Patent Halex halogen Halon heat Hoechst hydrocarbon hydrogen fluoride hydrogen-bond industry intermediates iodides isoflurane J. C. Tatlow Japanese Patent liquid crystals lubricants manufacture materials membranes molecular weight molecules monomers nucleophilic Offen Organofluorine Chemistry oxide oxygen perfluorinated perfluoroalkyl perfluorocarbon peroxide PFPE Phys polymer polymerization Pont production properties PTFE R. E. Banks radical reaction reactive reagents refrigeration resistance Rhône-Poulenc Scheme solubility solvent stability structure substitution substrate surfactants synthesis Table Telomer temperature tetrafluoroethylene thermal toxicity trifluoromethyl U.S. Patent vapor viscosity