Inorganic Syntheses, Volume 20The volumes in this continuing series provide a compilation of current techniques and ideas in inorganic synthetic chemistry. Includes inorganic polymer syntheses and preparation of important inorganic solids, syntheses used in the development of pharmacologically active inorganic compounds, small-molecule coordination complexes, and related compounds. Also contains valuable information on transition organometallic compounds including species with metal-metal cluster molecules. All syntheses presented here have been tested. |
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2,3-butanedione absorption acetate acetone acetonitrile acid added dropwise Anal aneN4 anhydrous aqueous bands benzene Calcd carbon carbonyl Caution CH₂ Chem Chemical chloride chloroform chromium chromium(III Cl₂ cm¹ cobalt cobalt(III compound cooled copper(I crystalline Department of Chemistry dichloromethane diethyl ether dimethyl sulfide dissolved distilled ester ethylenediamine evaporated extracted filtered H₂ H₂O heated at reflux hexane hydrogen hydrogen difluoride infrared Inorg iron(II isomer ligand lithium macrocyclic metal methanol methyl mixture is stirred mmole mole molybdenum N₂ nickel complexes nitrogen nmr spectrum obtained organic solvents Organomet oxide pentane perchlorate phosphine platinum complex platinum(II porphyrins potassium powder precipitate prepared Procedure Properties purity pyridine reaction reagent recrystallized residue rhenium rhodium room temperature round-bottomed flask salt Schlenk silica gel sodium solid soluble solution stable starting material sulfate Synth synthesis tetracyanoplatinate tetrahydrofuran tion torr trans tricarbonylcobalt tube vacuum washed yellow yield