Advances in Organometallic Chemistry, Volume 30Advances in Organometallic Chemistry |
Contents
| 1 | |
Chapter 2 Thermochromic Distibines and Dibismuthines | 77 |
Chapter 3 Syntheses Structures Bonding and Reactivity of Main Group Heterocarboranes | 99 |
Chapter 4 η2 Coordination of SiH σ Bonds to Transition Metals | 151 |
Chapter 5 Isoelectronic Organometallic Molecules | 189 |
Silicon Cations R3Si+ R3SI+ Nu and SileneType Species R2SiX as Intermediates | 243 |
| 309 | |
| 317 | |
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Common terms and phrases
acid alkyl alkynes American Chemical Society analogous Angew angle anion Anorg bond length boron cage carbenium carbenium ion carbon carborane cation Chem chemistry chloride closo cluster compounds coordination Copyright corresponding cyclopentadienyl Dalton Trans dibismuthines distance distibines electrophilic energy example formation geometry group 15 elements H. J. Breunig halide heterocarboranes hydride hydride ligand hydrogen Inorg intermediate intermolecular ionization isoelectronic isomer kinetic ligand lone pair LUMO M. F. Hawthorne M. I. Bruce main group mechanism metal atom metal center Mn—Si molecules N. S. Hosmane nonthermochromic nucleophilic observed Organomet Organometallics oxidative addition phosphine phosphine ligands plexes PMes PPh3 PPhy proton racemization react reaction reactivity Reprinted with permission ruthenium Scheme silane silicon silyl silylenium ion SiR3 solvent species spectra stability steric substitution T. P. Fehlner thermochromic three-center bond tion transition metal triphenylphosphine vinylidene complexes yield