Alkoxo and Aryloxo Derivatives of MetalsAlkoxo and Aryloxo Derivatives of Metals gives a comprehensive account of the chemistry of metal alkoxides and metal aryloxides, including their industrial applications such as microelectronics, ceramics, nonlinear optical materials, high-temperature superconductors, specialized glasses, and other advanced novel materials. It is an invaluable reference source book. The book is an updated edition of Metal Alkoxides, published by Academic Press in 1978, with additional coverage of metal aryloxides. It reflects the enormous growth in interest in this field in recent years. Alkoxo and aryloxo derivatives are organic compounds with metals for useful industrial purposes. Alkoxo and Aryloxo Derivatives of Metals will appeal to a wide-ranging audience, including university researchers and chemistry graduate students in industrial laboratories concerned with microelectronics, ceramics, glasses and other advanced novel materials; any laboratories doing research on nonlinear optical materials, high-temperature superconductors, ceramic materials, and specialized glasses. It can also serve as a supplementary text for final year courses in advanced inorganic chemistry, e.g., metallo-organic chemistry. |
Contents
| 1 | |
| 3 | |
Chapter 3 Heterometallic Alkoxides | 183 |
Chapter 4 XRay Crystal Structures of Alkoxo Metal Compounds | 229 |
Chapter 5 Metal Oxoalkoxides | 383 |
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Common terms and phrases
6-coord Acta addition alcohol alkali alkoxo alkyl aluminium appears aryloxides atoms axial benzene Bond angle Bond length bridging characterized chelating Chem chemistry Chim chloride Commun complex Compound Aryloxide compounds configuration containing continued coordination core corresponding D.C. Bradley Dalton Trans derivatives dimeric distorted electron example Figure five-coordinated Folting formation gave give groups heterometallic homoleptic hydrogen I.P. Rothwell Indian Inorg interesting involving isopropoxide J.C. Huffman lead ligands M.H. Chisholm metal alkoxides method methoxide mixed molecular molecule monomeric nature observed obtained octahedral Organomet Organometallics oxidation oxo-alkoxides oxygen P.E. Fanwick Polyhedron prepared presence R.C. Mehrotra reaction Reference reported respectively ring shown similar soluble solution solvents species spectra steric structure studies synthesis Table temperature terminal tetrahedral titanium transition unit values volatile W.E. Streib X-ray yield zirconium