Ruthenium Oxidation Complexes: Their Uses as Homogenous Organic Catalysts

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Springer Science & Business Media, Nov 3, 2010 - Science - 258 pages
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Ruthenium Oxidation Complexes explores ruthenium complexes, particularly those in higher oxidation states, which function as useful and selective organic oxidation catalysts. Particular emphasis is placed on those systems which are of industrial significance. The preparation, properties and applications of the ruthenium complexes are described, followed by a presentation of their oxidative properties and summary of the different mechanisms involved in the organic oxidations (e.g. oxidations of alcohols, alkenes, arenes and alkynes, alkanes, amines, ethers, phopshines and miscellaneous substrates). Moreover, future trends and developments in the area are discussed.

This monograph is aimed at inorganic, organic, industrial and catalysis chemists, especially those who wish to carry out specific organic oxidations using catalytic methods.

 

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Contents

The Chemistry of Ruthenium Oxidation Complexes
1
Oxidation of Alcohols Carbohydrates and Diols
135
Oxidation of Alkenes Arenes and Alkynes
173
Oxidation of Alkanes
215
Oxidations of Amines Amides Ethers Sulfides Phosphines Arsines Stibines and Miscellaneous Substrates
227
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